The following example is ambiguous:
template<typename T> int f(T&); template<typename T> int f(T&&); int i; int j = f(i);
Because of the special deduction rule for lvalues passed to rvalue-reference parameters, deduction produces f(int&) for both templates, and they are indistinguishable.
Because f(T&) accepts a strict subset of the things that f(T&&) does, it should be considered more specialized by the partial ordering rules.